Reaction #927265

ord-3dfad42c45c74ee49ecc62633e34e13e

Reaction equation

C#CCCCCCCCC
1-decyne
CCOC(=O)C=[N+]=[N-]
ethyl diazoacetate
→
CCCCCCCCC1=CC1C(=O)OCC
Ethyl 2-octylcycloprop-2-ene-1-carboxylate

Reactants

C#CCCCCCCCC
1-decyne
CCOC(=O)C=[N+]=[N-]
ethyl diazoacetate

Reagents

None

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Procedure

Ethyl 2-octylcycloprop-2-ene-1-carboxylate was prepared from 1-decyne and ethyl diazoacetate by the method of Mueller, P.; Pautex, N.; Helv. Chim Acta 1990, 73,1233.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06365549B2uspto-grants-2002_04