Reaction #742256

ord-b2b4d6eeae6e42398040644bb499ac19

Reaction equation

C=CCCCCCCCCOC(=O)C=C(C)c1ccc(N(CC)CC)cc1O
3-(4-diethylamino-2-hydroxy-phenyl)-but-2-enoic acid dec-9-enyl ester
CCOC(=O)C=C(C)c1ccc(N(CC)CC)cc1O
3-(4-diethylamino-2-hydroxy-phenyl)-but-2-enoic acid ethyl ester
C=CCCCCCCCCO
dec-9-en-1-ol
→
C=CCCCCCCCCOC(=O)/C=C(\C)c1ccc(N(CC)CC)cc1O
(E)-3(4-Diethylamino-2-hydroxy-phenyl)-but-2-enoic acid dec-9-enyl ester

Reactants

C=CCCCCCCCCOC(=O)C=C(C)c1ccc(N(CC)CC)cc1O
3-(4-diethylamino-2-hydroxy-phenyl)-but-2-enoic acid dec-9-enyl ester
—
tetraisopropyl-o-titanate
CCOC(=O)C=C(C)c1ccc(N(CC)CC)cc1O
3-(4-diethylamino-2-hydroxy-phenyl)-but-2-enoic acid ethyl ester
C=CCCCCCCCCO
dec-9-en-1-ol

Reagents

None

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Procedure

According to the same procedure, 3-(4-diethylamino-2-hydroxy-phenyl)-but-2-enoic acid dec-9-enyl ester was prepared from 3-(4-diethylamino-2-hydroxy-phenyl)-but-2-enoic acid ethyl ester, dec-9-en-1-ol and tetraisopropyl-o-titanate.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: USRE043006E1uspto-grants-2011_12