Reaction #692689

ord-66a5a839fabf48dca9dc5b99fa9c7074

Reaction equation

CCCN(CCC)c1ccc2nc3ccccc3[s+]c2c1.CCCN(CCC)c1ccc2nc3ccccc3[s+]c2c1.CCCN(CCC)c1ccc2nc3ccccc3[s+]c2c1.[I-].[I-].[I-]
3-(N,N-dipropylamino)-phenothiazin-5-ium triiodide
CCCCCCNCCCCCC
dihexylamine
→
CCCCCCN(CCCCCC)c1ccc2nc3ccc(N(CCC)CCC)cc3[s+]c2c1.[I-]
3-(N,N-dihexylamino)-7-(N,N-dipropylamino)-phenothiazin-5-ium iodide

Reactants

CCCN(CCC)c1ccc2nc3ccccc3[s+]c2c1.CCCN(CCC)c1ccc2nc3ccccc3[s+]c2c1.CCCN(CCC)c1ccc2nc3ccccc3[s+]c2c1.[I-].[I-].[I-]
3-(N,N-dipropylamino)-phenothiazin-5-ium triiodide
CCCCCCNCCCCCC
dihexylamine

Reagents

None

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Workup

  1. 1
    OtherThis compound was obtained
  2. 2
    OtherPrecipitation from dichloromethane
  3. 3
    workup.ADDITIONby addition of diethyl ether yielded purple lustrous crystals

Procedure

This compound was obtained following isolation of 3-(N,N-dipropylamino)-phenothiazin-5-ium triiodide and subsequent treatment with dihexylamine. Precipitation from dichloromethane by addition of diethyl ether yielded purple lustrous crystals. Mass spectrometry: C30H46N3OS requires m/z=480; found m/z=480 (I− not detected by mass spectrometry).

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07915254B2uspto-grants-2011_03