Reaction #62794

ord-5d1f8b2804ab4e34b1535c1ed036106d

Reaction equation

CCCCCCCC/C=C\CCCCCCCC(=O)O
oleic acid
CCCCCCCC/C=C\CCCCCCCC(=O)O
oleic acid
O=C([O-])[O-].[K+].[K+]
potassium carbonate
CCCCCCCC/C=C\CCCCCCCC(=O)[O-].[K+]
potassium oleate

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Workup

  1. 1
    Otherto obtain useful aqueous compositions wherein the anionic surface active agent
  2. 2
    Otheris formed in situ
  3. 3
    Otherwas prepared

Procedure

To demonstrate the ability to obtain useful aqueous compositions wherein the anionic surface active agent is formed in situ, an aqueous dispersion containing 1.86 percent kerosene, 0.14 percent commercial oleic acid, and 2 percent potassium carbonate was prepared. The amount of oleic acid was calculated to provide approximately 0.16 weight percent potassium oleate. Alfalfa treated with the resulting dispersion dried to a 25 percent moisture content in 22.4 hours whereas the control (alfalfa treated with water only) required 47.25 hours to reach the same moisture level. This represents a 53 percent reduction in drying time.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04762724uspto-grants-1988_08