Reaction #5396

ord-445013eb9d6b4372b91d441d2c130c81

Reaction equation

C=Cc1ccccc1
styrene
C=Cc1ccccc1C=C
divinylbenzene
O=C(OOC(=O)c1ccccc1)c1ccccc1
benzoyl peroxide
→
C=Cc1ccccc1.C=Cc1ccccc1C=C
Styrene-divinylbenzene

Reactants

C=Cc1ccccc1
styrene
C=Cc1ccccc1C=C
divinylbenzene
O=C(OOC(=O)c1ccccc1)c1ccccc1
benzoyl peroxide

Reagents

None

Solvents

Cc1ccccc1
toluene
CCCCCCCC
n-octane

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Workup

  1. 1
    workup.ADDITIONis introduced the monomer system
  2. 2
    Otherprepared separately
  3. 3
    workup.STIRRINGby stirring (350 rpm) for 10 hours at 80° C.

Procedure

It is stirred at room temperature for 30 minutes and then is introduced the monomer system prepared separately consisting of g 100 of styrene, g 67.5 of divinylbenzene (50%) in toluene (225 ml) and n-octane (75 ml) containing 3 g of benzoyl peroxide. The polymerization is carried out by stirring (350 rpm) for 10 hours at 80° C.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05244855uspto-grants-1993_09