Reaction #5142

ord-a6e9045e32c049c09013afb37b5d1d71

Reaction equation

Cc1cc(C)cc(Br)c1
5-bromo-m-xylene
C[Si](C)(C)Cl
chlorotrimethylsilane
→
Cc1cc(C)cc([Si](C)(C)C)c1
5-Trimethylsilyl-m-xylene

Reactants

Cc1cc(C)cc(Br)c1
5-bromo-m-xylene
C[Si](C)(C)Cl
chlorotrimethylsilane

Reagents

None

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Workup

  1. 1
    Otherafforded TSIX
  2. 2
    OtherThe yield

Procedure

In the same manner as described in preparation 1, 5-bromo-m-xylene was allowed to react with chlorotrimethylsilane, and afforded TSIX. The yield and properties of product are summarized in Table 1.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05243010uspto-grants-1993_09