Reaction #502064

ord-7e11e4253b7d44f2a2c4ac9c3e72ef63

Reaction equation

O=C([O-])[O-].[Ag+2]
Silver carbonate
O=S(=O)(O)CS(=O)(=O)O
methanedisulfonic acid
O=C([O-])[O-].[Ag+2]
silver carbonate
O=C=O
carbon dioxide
→
O=S(=O)([O-])CS(=O)(=O)[O-].[Ag+2]
silver methanedisulfonate
Yield 123.7%

Reactants

O=C([O-])[O-].[Ag+2]
Silver carbonate
O=S(=O)(O)CS(=O)(=O)O
methanedisulfonic acid
O=C([O-])[O-].[Ag+2]
silver carbonate
O=C=O
carbon dioxide

Reagents

None

Solvents

O
water

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Workup

  1. 1
    Otherany remaining insoluble material was removed by filtration
  2. 2
    Otherwas removed under vacuum

Procedure

Silver carbonate (20 g, 0.0725 moles) was added to methanedisulfonic acid (25.55 g 50% solution in water) and diluted in 25 mL of distilled water while stirring. The silver carbonate dissolved with effervescence of carbon dioxide. After the reaction was complete, any remaining insoluble material was removed by filtration and the filtrate was stripped of water was removed under vacuum to give 25.3 g of pure silver methanedisulfonate.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US08088548B2uspto-grants-2012_01