Reaction #487527

ord-63837604956d4726a6cfde2531fe8fe5

Reaction equation

$CCCCCCCC/C=C\CCCCCCCC(=O)Cl$

Oleoyl chloride

$CCCCCCCC/C=C\CCCCCCCCCCCC(=O)O$

Erucic acid

→

CCCCCCCCC=CCCCCCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC

Compound D

Yield 94.5%

Octadec-9-enoic acid docos-13-enyl ester

Yield 94.5%

Reactants

—

compounds D2

—

$CCCCCCCC/C=C\CCCCCCCC(=O)Cl$

Oleoyl chloride

$CCCCCCCC/C=C\CCCCCCCCCCCC(=O)O$

Erucic acid

—

compound D

Reagents

None

Solvents

Ethyl acetate Hexane

Conditions

Detailed conditions

See reaction.notes.procedure_details.

Procedure

Compound D was prepared from Oleoyl chloride and Erucic acid following the general procedure discussed before and as shown in FIG. 9. Pure compound D was a colorless oil obtained by column chromatography with Ethyl acetate/Hexane=1:40. Reaction conditions for branched derivative compounds D2, D3, and D4 are also shown below.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US08741822B2uspto-grants-2014_06