Reaction #433633

ord-17a7465a1e4348db8c123b7186989223

Reaction equation

Cl.Fc1cccc(COc2ccc3c(c2)CCNCC3)c1
7-(3-fluoro-benzyloxy)-2,3,4,5-tetrahydro-1H-benzo[d]azepine hydrochloride
COC(=O)Cl
methyl chloroformate
COC(=O)N1CCc2ccc(OCc3cccc(F)c3)cc2CC1
title compound
Yield 95.0%
COC(=O)N1CCc2ccc(OCc3cccc(F)c3)cc2CC1
7-(3-Fluoro-benzyloxy)-1,2,4,5-tetrahydro-benzo[d]azepine-3-carboxylic Acid Methyl Ester
Yield 95.0%

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Procedure

The title compound was prepared in analogy to Example 1d) from 7-(3-fluoro-benzyloxy)-2,3,4,5-tetrahydro-1H-benzo[d]azepine hydrochloride [Example 1c)] and methyl chloroformate with triethylamine as the base. Yield: 95% of theory as a colourless oil; MS: m/e=330 (M+H)+.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07173023B2uspto-grants-2007_02