Reaction #42009

ord-14f3f913e77e48958a13bba1bf02362b

Reaction equation

CCCCCCCC/C=C\CCCCCCCC(=O)O
oleic acid
CCO
ethanol
CCCCCCCC/C=C\CCCCCCCC(=O)OCC
ethyl oleate
Yield 90.0%

Solvents

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Workup

  1. 1
    Temperaturewas refluxed
  2. 2
    workup.ADDITIONwas added
  3. 3
    Filtrationthe catalyst was filtered off
  4. 4
    Concentrationconcentrated

Procedure

A mixture containing Catalyst A (0.05 g) and oleic acid (1.41 g, 5 mmol) and ethanol (10 ml) was refluxed with stirring for 40 h. On cooling ether (30 ml) was added and the catalyst was filtered off. The organic washings were combined and concentrated to give ethyl oleate as an oil (1.39 g, 90% yield).

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07728159B2uspto-grants-2010_06