Reaction #40855

ord-6657e0aca0cb44d894f6e71979dee592

Reaction equation

Cc1ccc(CC(=O)c2ccccc2)cc1
1-phenyl-2-p-tolylethanone
COC(OC)N(C)C
dimethylformamide dimethylacetal
Cc1ccc(/C(=C\N(C)C)C(=O)c2ccccc2)cc1
title compound
Cc1ccc(/C(=C\N(C)C)C(=O)c2ccccc2)cc1
(E)-3-(Dimethylamino)-1-phenyl-2-p-tolylprop-2-en-1-one

Solvents

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Workup

  1. 1
    OtherSolvents were removed under high vacuum

Procedure

A solution of 1-phenyl-2-p-tolylethanone (2 g, 9.5 mmol) and dimethylformamide dimethylacetal (4.5 g, 38.1 mmol) in DMF (30 ml) was heated at 75° C. for 24 hours. Solvents were removed under high vacuum to obtain the title compound as a yellow oil, which was used directly in the next step without purification.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07728014B2uspto-grants-2010_06