Reaction #367103

Reaction equation

allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride

allylamine

→

Allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid N-allylimide

Conditions

Workup

1. 1
   Temperatureis heated
2. 2
   Temperatureat reflux temperature for 2 hours
3. 3
   workup.DISTILLATIONwater is distilled off
4. 4
   Otheris rectified at 119°-127° C.

Procedure

A mixture of 30 g of allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride and 9.41 g of allylamine is heated at reflux temperature for 2 hours, water is distilled off and the product is rectified at 119°-127° C. and 2.66 Pa. This gives 30.24 g (85.5% of theory) of a pale yellow oil having the following characteristic data: n20 =1.5202, η25 =0.135 Pa.s.

Source