Reaction #302879

ord-480eeee1e94949eab8564a608a63afe1

Reaction equation

[Cl-].[Cl-].[Mg+2]
magnesium chloride
C[CH2][K].O=C(O)CC(=O)O
ethyl potassium malonate
→
O=C([O-])CC(=O)[O-].[CH2]C.[Mg+2]
Ethyl Magnesium Malonate

Reactants

[Cl-].[Cl-].[Mg+2]
magnesium chloride
C[CH2][K].O=C(O)CC(=O)O
ethyl potassium malonate

Reagents

None

Solvents

CC(C)O
isopropanol

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Workup

  1. 1
    FiltrationAfter filtration, ethyl magnesium malonate
  2. 2
    Otherwas dried in vacuo

Procedure

To a stirred aqueous solution of 1.5 M magnesium chloride and 3 M ethyl potassium malonate was added five volumes of isopropanol. After filtration, ethyl magnesium malonate was dried in vacuo.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US08192952B2uspto-grants-2012_06