Reaction #2389089

ord-7c62683e26604d96836ca3df37c8dc5f

Reaction equation

CCCCCCCCCCCCS
dodecane thiol
O=S(=O)(Cl)Cl
sulfuryl chloride
→
CCCCCCCCCCCCSCl
dodecansulfenyl chloride

Reactants

CCCCCCCCCCCCS
dodecane thiol
O=S(=O)(Cl)Cl
sulfuryl chloride

Reagents

None

Solvents

ClC(Cl)Cl
CHCl3

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Workup

  1. 1
    OtherRemoval of solvent (aspirator)

Procedure

To a solution of dodecane thiol (1.00 mL, 4.17 mmol, Aldrich Chemical Company) in 20 mL CHCl3 was added sulfuryl chloride (0.74 mL, 9.18 mmol, Aldrich Chemical Company), and the resulting mixture was stirred at room temperature for 18 h. Removal of solvent (aspirator), afforded dodecansulfenyl chloride that was determined to be sufficiently pure by 1H NMR.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06429200B1uspto-grants-2002_08