Reaction #2389088

ord-b0efa6536ab549168c50a7543b527c4e

Reaction equation

CCCCCCCCCCCCS
dodecane thiol
[Cl-]
chloride
→
CCCCCCCCCCCCSCl
dodecansulfenyl chloride

Reactants

CCCCCCCCCCCCS
dodecane thiol
[Cl-]
chloride

Reagents

None

Solvents

ClC(Cl)Cl
CHCl3

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Workup

  1. 1
    OtherRemoval of solvent (aspirator)

Procedure

To a solution of dodecane thiol (1.00 mL, 4.17 mmol, Aldrich) in 20 mL CHCl3 was added suliryl chloride (0.74 mL, 9.19 mmol, Aldrich), and the regulting mixture was stirred at room temperature for 18 h. Removal of solvent (aspirator), afforded dodecansulfenyl chloride that was determined to be sufficiently pure by 1H NMR.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06429200B1uspto-grants-2002_08