Reaction #2371343

ord-5256a00cff5c4ee89eaf09deba527bf8

Reaction equation

Nc1ccc(-c2ccc(N)c(N)c2)cc1N
3,3′-diaminobenzidine
CN(C)c1ccc(C=CC=O)cc1
3-(4-dimethylaminophenyl)acrylaldehyde
→
CN(C)c1ccc(/C=C/c2nc3cc(-c4ccc5nc(/C=C/c6ccc(N(C)C)cc6)[nH]c5c4)ccc3[nH]2)cc1
Compound 264
CN(C)c1ccc(/C=C/c2nc3cc(-c4ccc5nc(/C=C/c6ccc(N(C)C)cc6)[nH]c5c4)ccc3[nH]2)cc1
4,4′-((1E,1′E)-1H,3′H-[5,5′-bibenzo[d]imidazole]-2,2′-diylbis(ethene-2,1-diyl))bis(N,N-dimethylaniline)

Reactants

Nc1ccc(-c2ccc(N)c(N)c2)cc1N
3,3′-diaminobenzidine
CN(C)c1ccc(C=CC=O)cc1
3-(4-dimethylaminophenyl)acrylaldehyde

Reagents

None

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Procedure

Compound 264 was prepared according to the procedure similar to that described in Scheme III from 3,3′-diaminobenzidine and 3-(4-dimethylaminophenyl)acrylaldehyde. [M+H]+ calcd for C34H32N6: 525.27; found: 525.59.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US09144557B2uspto-grants-2015_09