Reaction #2329040

ord-a033880df3c848cfbf8807a3cf38d580

Reaction equation

CCCCCCCCCCCCOc1ccc(CCl)cc1
4-dodecyloxybenzyl chloride
O=S(Cl)Cl
thionyl chloride
CCCCCCCCCCOc1ccc(CO)cc1
4-decyloxybenzyl alcohol
→
CCCCCCCCCCOc1ccc(CCl)cc1
4-Decyloxybenzyl Chloride

Reactants

—
white solid
CCCCCCCCCCCCOc1ccc(CCl)cc1
4-dodecyloxybenzyl chloride
O=S(Cl)Cl
thionyl chloride
CCCCCCCCCCOc1ccc(CO)cc1
4-decyloxybenzyl alcohol

Reagents

None

Solvents

ClCCl
CH2Cl2

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Workup

  1. 1
    OtherWas synthesized

Procedure

Was synthesized following the same general procedure as that for the preparation of 4-dodecyloxybenzyl chloride; thionyl chloride (5.00 g, 42.4 mmol), 4-decyloxybenzyl alcohol (10.2 g, 38.6 mmol), CH2Cl2 (100 mL). 9.87 g (90%) white solid which decomposes upon melting.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07671033B2uspto-grants-2010_03