Reaction #216533

ord-4203c6a9fba94503954105786deaf8d7

Reaction equation

[Cl-].[Na+]
sodium chloride
[Cl-].[K+]
potassium chloride
[Cl-].[K+]
potassium chloride
[Cl-].[Na+]
sodium chloride
O=P([O-])([O-])[O-]
phosphate
O=P([O-])(O)O.[K+]
potassium dihydrogen phosphate
O=P([O-])(O)O.[Na+]
sodium dihydrogen phosphate

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Procedure

The fine particles of potassium chloride or sodium chloride and the fine particles of phosphate or a buffering agent may be separately prepared. For example, when a concentrated aqueous solution of potassium chloride or sodium chloride is formed, an aqueous solution of potassium dihydrogen phosphate and sodium dihydrogen phosphate (4:6 in molar ratio) can be separately formed. Both solutions are preferably in a saturation state, which provides a greater amount of fine particles, i.e., a high efficiency. Note that the weighed phosphates must be completely dissolved in water, because the proportion of the dissolved phosphates significantly affects the pH value. The thus-prepared aqueous solutions are poured into an organic solvent such as ethanol, in the same manner as described above, respectively, and the precipitated fine particles are collected.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05468408uspto-grants-1995_11