Reaction #1914842

ord-29cfeff9120e4d8ebc545bbaee17cc15

Reaction equation

CCOc1ccc(Cc2c(O[C@@H]3O[C@H](CO)[C@@H](O)[C@H](O)[C@H]3O)n[nH]c2C)cc1
4-[(4-ethoxyphenyl)methyl]-5-methyl-3-(β-D-glucopyranosyloxy)-1H-pyrazole
CCI
iodoethane
→
CCOc1ccc(Cc2c(O[C@@H]3O[C@H](CO)[C@@H](O)[C@H](O)[C@H]3O)nn(CC)c2C)cc1
title compound
CCOc1ccc(Cc2c(O[C@@H]3O[C@H](CO)[C@@H](O)[C@H](O)[C@H]3O)nn(CC)c2C)cc1
1-Ethyl-4-[(4-ethoxyphenyl)methyl]-3-(β-D-glucopyranosyloxy)-5-methylpyrazole

Reactants

CCOc1ccc(Cc2c(O[C@@H]3O[C@H](CO)[C@@H](O)[C@H](O)[C@H]3O)n[nH]c2C)cc1
4-[(4-ethoxyphenyl)methyl]-5-methyl-3-(β-D-glucopyranosyloxy)-1H-pyrazole
CCI
iodoethane

Reagents

None

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Procedure

The title compound was prepared in a similar manner to that described in Example 61 using 4-[(4-ethoxyphenyl)methyl]-5-methyl-3-(β-D-glucopyranosyloxy)-1H-pyrazole instead of 3-(β-D-glucopyranosyloxy)-4-[(4-isopropoxyphenyl)methyl]-5-methyl-1H-pyrazole and using iodoethane instead of iodopropane.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07056892B2uspto-grants-2006_06