Reaction #1914808

ord-8b1fceff48664a4faa7ec72f72884b23

Reaction equation

Cc1cccc(O)c1
3-methylphenol
O=N[O-].[Na+]
sodium nitrite
→
CC1=CC(=O)C=CC1=NO
3-Methyl-1,4-benzoquinone-4-oxime

Reactants

Cc1cccc(O)c1
3-methylphenol
O=N[O-].[Na+]
sodium nitrite

Reagents

None

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Procedure

3-Methyl-1,4-benzoquinone-4-oxime was prepared by reaction of 3-methylphenol with sodium nitrite under basic conditions by the method of T. Ishikawa et al. described in Tetrahedron 31, 1995, page 8454.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07056349B2uspto-grants-2006_06