Reaction #1904077
ord-1df92e4082ec46008979c49fbec67e32
Reaction equation
methyl 2-amino-5-bromobenzoate
2-thienyllithium
→
(2-Amino-5-bromophenyl)(dithien-2-yl)methanol
Reagents
None
Conditions
Detailed conditions
See reaction.notes.procedure_details.
Procedure
Prepared from methyl 2-amino-5-bromobenzoate and 2-thienyllithium using the procedure similar to example 6. 1H-NMR (CDCl3) δ 7.35 (dd, J=5.3, 1.1 Hz, 2H), 7.26 (dd, J=8.4, 2.3 Hz, 1H), 6.98 (m, 2H), 6.82 (d, J=2.3 Hz, 1H), 6.79 (m, 2H), 6.62 (d, J=8.4 Hz, 1H), 5.45 (br s, 1H), 3.86 (br s, 2H); Anal. Calc. For C15H12BrNOS2: C, 49.18, H, 3.30; N, 3.82. Found: C, 49.62, H, 3.47; N, 3.60.