Reaction #1797472

ord-7338affa70ff445b8d0a9b1dcee742d4

Reaction equation

O.O.O.O.O.O.O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Bi+3]
bismuth nitrate hexahydrate
O=C(O)CN(CCN(CC(=O)O)CC(=O)O)CC(=O)O
EDTA
→
O=C(O)CN(CCN(CC(=O)O)CC(=O)O)CC(=O)O.[Bi]
Bismuth EDTA

Reactants

O.O.O.O.O.O.O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Bi+3]
bismuth nitrate hexahydrate
O=C(O)CN(CCN(CC(=O)O)CC(=O)O)CC(=O)O
EDTA

Reagents

None

Solvents

[NH4+].[OH-]
ammonium hydroxide

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Workup

  1. 1
    OtherA precursor solution is prepared
  2. 2
    Temperatureunder reflux until a clear solution
  3. 3
    Otherresults

Procedure

A precursor solution is prepared by mixing 2.425 g of bismuth nitrate hexahydrate into 10 ml of 28% ammonium hydroxide solution containing 2 g of EDTA (ethylene diamine tetraacetic acid-sodium salt) under reflux until a clear solution results.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07790137B2uspto-grants-2010_09