Reaction #1328433

ord-d3d5ca1b69dd40d780e80fce0b4610ff

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Procedure

A mixture of 2 mmol of p-xylene, 0.1 mmol of N-acetoxyphthalimide, 0.01 mmol of cobalt(II) acetate, 0.01 mmol of manganese(II) acetate and 2 ml of acetic acid was stirred at 100° C. in an atmosphere of oxygen gas (1 atm=0.1 MPa) for 14 hours and thereby yielded terephthalic acid, p-toluic acid and p-carboxybenzaldehyde in yields of 79%, 8% and 5%, respectively.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07115541B2uspto-grants-2006_10