Reaction #1265369

ord-9ddddc4f8b124809a4e0345279e96eed

Reaction equation

COc1cc(N)cc(OC)c1OC
3,4,5-trimethoxyaniline
Nc1cc(C(=O)O)cc(C(=O)O)c1
3,5-dicarboxy-aniline
COC1CCC(N)C(OC)C1OC
2,3,4-trimethoxycyclohexylamine

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Procedure

3,4,5-trimethoxyaniline was hydrogenated via the procedure given for 3,5-dicarboxy-aniline to provide 2,3,4-trimethoxycyclohexylamine which was coupled to the C-terminal valine in the standard way.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07276484B2uspto-grants-2007_10