Reaction #1265346

ord-b3732b1a12f34214af433e10a89d58db

Reaction equation

O=S(=O)([O-])[O-].O=S(=O)([O-])[O-].O=S(=O)([O-])[O-].[Al+3].[Al+3]
aluminum sulfate
O=S(=O)([O-])[O-].[Zn+2]
zinc sulfate
O=C([O-])[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.[K+]
potassium gluconate
O=C([O-])[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.[K+]
potassium gluconate
→
O=C([O-])[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.O=C([O-])[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.[Zn+2]
zinc gluconate

Reactants

O=S(=O)([O-])[O-].O=S(=O)([O-])[O-].O=S(=O)([O-])[O-].[Al+3].[Al+3]
aluminum sulfate
—
phospholipids
O=S(=O)([O-])[O-].[Zn+2]
zinc sulfate
O=C([O-])[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.[K+]
potassium gluconate
—
lecithin
O=C([O-])[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.[K+]
potassium gluconate
—
20

Reagents

None

Solvents

O
water
O
water
O
water

Conditions

Temperature
95°CELSIUS
Detailed conditions
See reaction.notes.procedure_details.

Workup

  1. 1
    workup.ADDITIONmixed
  2. 2
    workup.ADDITIONuntil well dispersed
  3. 3
    workup.ADDITIONthen added to the above mixture
  4. 4
    workup.ADDITIONmixed for 10 minutes
  5. 5
    workup.ADDITIONwas added dropwise
  6. 6
    Temperatureheated to 50° C.
  7. 7
    workup.ADDITIONthen added to the above mixture
  8. 8
    workup.ADDITIONmixed for 10 minutes
  9. 9
    workup.STIRRINGWhile this was being stirred
  10. 10
    workup.ADDITIONwas added dropwise
  11. 11
    FiltrationThe product was filtered with suction
  12. 12
    Washby rinsing with purified water
  13. 13
    Othera temperature of 100° C.
  14. 14
    OtherThe cake was crushed
  15. 15
    Temperatureafter cooling

Procedure

One hundred grams of mica pigment was added to 450 ml of water and mixed using a home type mixer until well dispersed. Three grams of hydrogenated egg yolk lecithin (phospholipids 30%, neutral fat 70%) having an HLB value of 2 was dissolved in 100 ml of water heated at 95° C. then added to the above mixture and mixed for 10 minutes. While this was being stirred, 2 chemical equivalents of aluminum sulfate aqueous solution, based on the phospholipids, was added dropwise. Four grams of potassium gluconate having an HLB value of 20 was dissolved in 50 ml of water heated to 50° C. then added to the above mixture and mixed for 10 minutes. While this was being stirred, 2 chemical equivalents of zinc sulfate aqueous solution, based on the potassium gluconate, was added dropwise. The product was filtered with suction using a Buchner funnel, followed by rinsing with purified water. The filter cake was then baked in an oven for 3 hours after the filter cake reached a temperature of 100° C. to further dehydrate the filter cake. The cake was crushed and pulverized to a powder after cooling. This resulted in a mica pigment chemically immobilized with lecithin and zinc gluconate.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07276113B2uspto-grants-2007_10