Reaction #1256748

ord-04122c5af7d14a4aaaf94575c9ab43ee

Reaction equation

CC(C)[SiH](CC(C)(C)C)C(C)C
Compound 51a
CC(C)[SiH](CC(C)(C)C)C(C)C
Diisopropyl(2,2-dimethylpropyl)silane
CC(C)CCBr
1-bromo-3-methylbutane
→
CC(C)CC[SiH](C(C)C)C(C)C
Compound 53a
CC(C)CC[SiH](C(C)C)C(C)C
(3-Methylbutyl)diisopropylsilane

Reactants

CC(C)[SiH](CC(C)(C)C)C(C)C
Compound 51a
CC(C)[SiH](CC(C)(C)C)C(C)C
Diisopropyl(2,2-dimethylpropyl)silane
CC(C)CCBr
1-bromo-3-methylbutane

Reagents

None

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Procedure

The procedure of synthesizing Compound 51a was repeated, except that 1-bromo-3-methylbutane (12.6 mL, 100 mmol) was employed, whereby the Compound 53a was obtained as a colorless liquid (12.6 g, 73%).

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07825103B2uspto-grants-2010_11