Reaction #1231

ord-9a85735f44d44b4dad4458afbbf407f8

Reaction equation

COC(=O)c1ccc(-c2ccc3cc(O)c(C45CC6CC(CC(C6)C4)C5)cc3c2)cc1
methyl 4-[7-(1-adamantyl)-6-hydroxy-2-naphthyl]benzoate
COCCOCCl
methoxyethoxymethyl chloride
COCCOCOc1cc2ccc(-c3ccc(C(=O)OC)cc3)cc2cc1C12CC3CC(CC(C3)C1)C2
expected compound
Yield 55.0%
COCCOCOc1cc2ccc(-c3ccc(C(=O)OC)cc3)cc2cc1C12CC3CC(CC(C3)C1)C2
methyl 4-[7-(1-adamantyl)-6-methoxyethoxymethoxy-2-naphthyl]benzoate
Yield 55.0%

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Procedure

Following the basic procedure of Example 12, by reacting 980 mg (2.4 mmol) of methyl 4-[7-(1-adamantyl)-6-hydroxy-2-naphthyl]benzoate with 330 μl (28.6 mmol) of methoxyethoxymethyl chloride, 650 mg (55%) of the expected compound were obtained in the form of an oil.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05723499uspto-grants-1998_03