Reaktion #992696

ord-4f35ba68c5da457ab8339458b719f25e

Reaktionsgleichung

O=C/C(Br)=C(/Br)C(=O)O
Mucobromic acid
N=C(N)NN.O=C(O)O
Aminoguanidine bicarbonate
O=C=O
carbon dioxide
→
NNC(N)=[NH2+].O=C/C(Br)=C(/Br)C(=O)[O-]
Aminoguanidinium Mucobromate

Edukte

O=C/C(Br)=C(/Br)C(=O)O
Mucobromic acid
N=C(N)NN.O=C(O)O
Aminoguanidine bicarbonate
O=C=O
carbon dioxide

Reagenzien

Keine

Lösungsmittel

O
water

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    SonstigeThe water was removed in vacuo
  2. 2
    Temperaturwith heating to approximately 90° C
  3. 3
    SonstigeThe product was isolated as an off-white solid

Vorschrift

Mucobromic acid (2.0 g, 7.76 mmol) was dissolved in 10 ml of distilled water. Aminoguanidine bicarbonate (1.06 g, 7.76 mmol) was added in portions at room temperature (carbon dioxide gas was evolved) and the reaction was stirred at room temperature for 18 hours. The water was removed in vacuo with heating to approximately 90° C. The product was isolated as an off-white solid.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US08012277B2uspto-grants-2011_09