Reaktion #991111

Reaktionsgleichung

2-ethylhexylamine

β-methylcrotonyl chloride

→

N-(2-ethylhexyl)-β-methylcrotonamide

Ausbeute 83.3%

Lösungsmittel

n-hexane

Reaktionsbedingungen

Aufarbeitung

1. 1
   SonstigeAfter reaction
2. 2
   Waschenthe reaction mixture was washed first with diluted hydrochloric acid
3. 3
   Trocknenwith 10% sodium hydroxide solution and subsequently dried with sodium sulfate
4. 4
   workup.DISTILLATIONThe solvent was distilled off
5. 5
   workup.DISTILLATIONthe residue was further distilled in vacuum
6. 6
   Sonstigewas collected

Vorschrift

In 20 ml of n-hexane was dissolved 1.40 g (0.011 mol) of 2-ethylhexylamine. With stirring, 1.20 g (0.01 mol) of β-methylcrotonyl chloride was added to the solution. After reaction, the reaction mixture was washed first with diluted hydrochloric acid and then with 10% sodium hydroxide solution and subsequently dried with sodium sulfate. The solvent was distilled off and the residue was further distilled in vacuum. A fraction having a boiling point of 133°-134° C./l mmHg was collected, obtaining 1.76 g of N-(2-ethylhexyl)-β-methylcrotonamide as an oil (yield: 82.3%). Usual analysis was carried out to identify the compound. The results are shown below.

Quelle