Reaktion #955905

Reaktionsgleichung

3-(1′-hydroxyoctadecyloxy)-4,5-dioctadecyloxy nitrobenzene

acryl chloride

→

3-(1′-acryloyloxyoctadecyloxy)-4,5-dioctadecyloxy nitrobenzene

Ausbeute 92.2%

Lösungsmittel

pyridine

Reaktionsbedingungen

Aufarbeitung

1. 1
   Sonstigecontrolled at 0° C.
2. 2
   workup.DISSOLUTIONdissolved
3. 3
   Sonstigethe reaction
4. 4
   Sonstigeresulting solution
5. 5
   Sonstigewas purified via silica gel chromatography (mix solvent of hexane and ethyl acetate)

Vorschrift

Subsequently, into pyridine controlled at 0° C., dissolved was 4.0 g of 3-(1′-hydroxyoctadecyloxy)-4,5-dioctadecyloxy nitrobenzene and added 0.50 g of acryl chloride for 30 minutes, followed by stirring 1 hour at room temperature. After finishing the reaction, resulting solution was purified via silica gel chromatography (mix solvent of hexane and ethyl acetate) to obtain 3.9 g of 3-(1′-acryloyloxyoctadecyloxy)-4,5-dioctadecyloxy nitrobenzene (yield: 92%).

Quelle