Reaktion #954424

ord-084ebc44b0d54570a09af1edeb192b2e

Reaktionsgleichung

C[N+](C)(CCCNC=O)CC(=O)Nc1ccc([N+](=O)[O-])cc1.[Cl-]
N,N-dimethyl-N-(4-nitrophenyl)carbamylmethyl-N-3-formamidopropylammonium chloride
→
C[N+](C)(CCCNC=O)CC(=O)Nc1ccc(N)cc1.[Cl-]
N,N-dimethyl-N-(4-aminophenyl)carbamylmethyl-N-3-formamidopropylammonium chloride

Edukte

—
1c
C[N+](C)(CCCNC=O)CC(=O)Nc1ccc([N+](=O)[O-])cc1.[Cl-]
N,N-dimethyl-N-(4-nitrophenyl)carbamylmethyl-N-3-formamidopropylammonium chloride

Reagenzien

[S]=[Pt]
platinum sulfide

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Following the procedure described in 1c above, N,N-dimethyl-N-(4-nitrophenyl)carbamylmethyl-N-3-formamidopropylammonium chloride was catalytically hydrogenated in aqueous solution at 70°-75° C. and at 600 pounds per square inch in the presence of a 5 percent platinum sulfide on charcoal mixture to obtain N,N-dimethyl-N-(4-aminophenyl)carbamylmethyl-N-3-formamidopropylammonium chloride.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04103092uspto-grants-1978_07