Reaktion #95303

ord-3a8f39dadf9d4b60a1e83258cc1ccea6

Reaktionsgleichung

C#CC(CCCCCCC)OC(c1ccccc1)(c1ccccc1)c1ccccc1
3-triphenylmethoxy-1-decyne
CC(C)C(C)BC(C)C(C)C
disiamylborane
[Br-]
bromide
→
CCCCCCCC(/C=C/Br)OC(c1ccccc1)(c1ccccc1)c1ccccc1
title compound
CCCCCCCC(/C=C/Br)OC(c1ccccc1)(c1ccccc1)c1ccccc1
1-bromo-3-triphenylmethoxy-trans-1-decene

Edukte

C#CC(CCCCCCC)OC(c1ccccc1)(c1ccccc1)c1ccccc1
3-triphenylmethoxy-1-decyne
CC(C)C(C)BC(C)C(C)C
disiamylborane
[Br-]
bromide

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Treatment of 3-triphenylmethoxy-1-decyne (Example 129) with disiamylborane and the bromide by the procedure described in Example 1173 is productive of the title compound.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04343949uspto-grants-1982_08