Reaktion #95290

ord-1fa9a87d56c3413db2b1af374588a12a

Reaktionsgleichung

CCCCC(C)(C)C(O)/C=C/I
4,4-dimethyl-1-iodo-trans-1-octen-3-ol
BrC(c1ccccc1)(c1ccccc1)c1ccccc1
triphenylmethyl bromide
→
CCCCC(C)(C)C(/C=C/I)OC(c1ccccc1)(c1ccccc1)c1ccccc1
title compound
CCCCC(C)(C)C(/C=C/I)OC(c1ccccc1)(c1ccccc1)c1ccccc1
4,4-dimethyl-1-iodo-3-triphenylmethoxy-trans-1-octene

Edukte

CCCCC(C)(C)C(O)/C=C/I
4,4-dimethyl-1-iodo-trans-1-octen-3-ol
BrC(c1ccccc1)(c1ccccc1)c1ccccc1
triphenylmethyl bromide

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Sonstigeof pyridine and purification on Florisil®

Vorschrift

Treatment of 11.2 g. (0.0396 mole) of 4,4-dimethyl-1-iodo-trans-1-octen-3-ol (Example 996) with 12.8 g. of triphenylmethyl bromide in 50 ml. of pyridine and purification on Florisil®, all as described in Example 728 gives the title compound.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04343949uspto-grants-1982_08