Reaktion #95245

ord-bcf19da25ebc403ebedb533e1153cc41

Reaktionsgleichung

CCC(CCCCCC1=CCCC1=O)(C(=O)O)C(=O)O.O/N=C/c1cc[n+](C[n+]2ccc(/C=N/O)cc2)cc1.[Br-].[Br-]
2-(6,6-dicarboxyoctyl)-2-cyclopentenone methoxime
→
CCC(CCCCCC1=CCCC1=O)C(=O)O.O/N=C/c1cc[n+](C[n+]2ccc(/C=N/O)cc2)cc1.[Br-].[Br-]
2-(6-carboxyoctyl)-2-cyclopentenone methoxime

Edukte

CCC(CCCCCC1=CCCC1=O)(C(=O)O)C(=O)O.O/N=C/c1cc[n+](C[n+]2ccc(/C=N/O)cc2)cc1.[Br-].[Br-]
2-(6,6-dicarboxyoctyl)-2-cyclopentenone methoxime

Reagenzien

Keine

Lösungsmittel

Cc1ccccc1C
xylene

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Temperaturat reflux for 18 hours
  2. 2
    Sonstigegives a yellow oil

Vorschrift

In the manner described in Example 21, treatment of 2-(6,6-dicarboxyoctyl)-2-cyclopentenone methoxime (Example 28) with xylene at reflux for 18 hours gives a yellow oil.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04343949uspto-grants-1982_08