Reaktion #95089

ord-a940daad3d79418481407d0e47d832cf

Reaktionsgleichung

CC(=CC(=O)O)c1cccc([N+](=O)[O-])c1
3-(3-nitrophenyl)-2-butenoic acid
CCOC(=O)Cl
ethyl chloroformate
CCCCCCCCCC(C)N
1-methyldecylamine
→
CCCCCCCCCC(C)NC(=O)C=C(C)c1cccc([N+](=O)[O-])c1
title product
Ausbeute 72.0%
CCCCCCCCCC(C)NC(=O)C=C(C)c1cccc([N+](=O)[O-])c1
N-(1-Methyldecyl)-3-(3-Nitrophenyl)-2-butenamide
Ausbeute 72.0%

Edukte

CC(=CC(=O)O)c1cccc([N+](=O)[O-])c1
3-(3-nitrophenyl)-2-butenoic acid
CCOC(=O)Cl
ethyl chloroformate
CCCCCCCCCC(C)N
1-methyldecylamine

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Sonstigeaccording to the procedure of Preparation 22

Vorschrift

The 3-(3-nitrophenyl)-2-butenoic acid from Preparation 12 having a melting point of 147°-149° C. was reacted with ethyl chloroformate, followed by 1-methyldecylamine, according to the procedure of Preparation 22. This afforded a 72% yield of the title product.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04343813uspto-grants-1982_08