Reaktion #95085

Reaktionsgleichung

3-(3-nitrophenyl)propenoic acid

thionyl chloride

→

title compound

Ausbeute 91.0%

3-(3-Nitrophenyl)propenoyl Chloride

Ausbeute 91.0%

Lösungsmittel

benzene

Reaktionsbedingungen

Aufarbeitung

1. 1
   workup.ADDITIONA mixture of 50 g
2. 2
   Temperaturunder reflux for 2.5 hours
3. 3
   FiltrationThe cooled solution was filtered
4. 4
   Sonstigeit was evaporated in vacuo
5. 5
   SonstigeThe residue was recrystallized from carbon tetrachloride
6. 6
   Sonstigeto give 49.9 g

Vorschrift

A mixture of 50 g. of 3-(3-nitrophenyl)propenoic acid, 24.54 ml. of thionyl chloride and 300 ml. of benzene were heated under reflux for 2.5 hours. The cooled solution was filtered and then it was evaporated in vacuo. The residue was recrystallized from carbon tetrachloride, to give 49.9 g. (91% yield) of the title compound, m.p. 81°-83.5° C.

Quelle