Reaktion #950213

ord-906ce87afbf049a2a9cd3eeb7dfdceba

Reaktionsgleichung

O=C1CCCN(C(=O)c2ccc([N+](=O)[O-])cc2)c2cccnc21
5,6,7,8-tetrahydro-5-(4-nitrobenzoyl)-9H-pyrido[3,2-b]azepin -9-one
CN(C)C(OC(C)(C)C)N(C)C
tert-butoxybis(dimethylamino)methane
→
CN(C)C=C1CCN(C(=O)c2ccc([N+](=O)[O-])cc2)c2cccnc2C1=O
product
CN(C)C=C1CCN(C(=O)c2ccc([N+](=O)[O-])cc2)c2cccnc2C1=O
8[(Dimethylamino)methylene]-5,6,7,8-tetrahydro-5-(4-nitrobenzoyl)-9H-pyrido[3,2-b]azepin-9-one

Edukte

O=C1CCCN(C(=O)c2ccc([N+](=O)[O-])cc2)c2cccnc21
5,6,7,8-tetrahydro-5-(4-nitrobenzoyl)-9H-pyrido[3,2-b]azepin -9-one
CN(C)C(OC(C)(C)C)N(C)C
tert-butoxybis(dimethylamino)methane

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

As described for Reference Example 221, 5,6,7,8-tetrahydro-5-(4-nitrobenzoyl)-9H-pyrido[3,2-b]azepin -9-one is reacted with tert-butoxybis(dimethylamino)methane to give the product as a solid.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05719278uspto-grants-1998_02