Reaktion #950

Reaktionsgleichung

triphenylphosphine

3,3,3-trifluoropropyl iodid

→

solid

Ausbeute 76.5%

(3,3,3-Trifluoropropyl)triphenylphosphonium iodide

Ausbeute 76.5%

Lösungsmittel

Reaktionsbedingungen

Aufarbeitung

1. 1
   SonstigeThe solid which formed
2. 2
   Filtrationwas filtered
3. 3
   Waschenwashed with xylenes
4. 4
   Sonstigeair dried

Vorschrift

A solution of triphenylphosphine (Aldrich, 11.7 g) and 3,3,3-trifluoropropyl iodid (Lancaster, 10 g) was vigorously refluxed in xylenes (75 mL) for 2 days. The solid which formed was filtered and washed with xylenes then air dried to yield a white solid (16.6 g). 1H NMR and elemental analysis are consistent with the proposed structure.

Quelle