Reaktion #94981

ord-a34c3fd1c18c4fd6a479e28b391720eb

Reaktionsgleichung

O=[N+]([O-])[O-].[Na+]
Sodium nitrate
O=[N+]([O-])OCC(CO[N+](=O)[O-])(CO[N+](=O)[O-])CO[N+](=O)[O-]
Pentaerythritol tetranitrate
O=[N+]([O-])OCC(CO[N+](=O)[O-])(CO[N+](=O)[O-])CO[N+](=O)[O-]
PETN
→
OCC(CO)(CO)CO
pentaerythritol

Edukte

O=[N+]([O-])[O-].[Na+]
Sodium nitrate
O=[N+]([O-])OCC(CO[N+](=O)[O-])(CO[N+](=O)[O-])CO[N+](=O)[O-]
Pentaerythritol tetranitrate
O=[N+]([O-])OCC(CO[N+](=O)[O-])(CO[N+](=O)[O-])CO[N+](=O)[O-]
PETN

Reagenzien

Keine

Lösungsmittel

O
water

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Sonstigewas incorporated into the emulsion at 23° C. by gentle stirring
  2. 2
    Sonstigeat 23° C.

Vorschrift

Sodium nitrate (400 grams) which had been ground in a ball mill and screened through a 35-mesh (Tyler) screen was incorporated into the emulsion at 23° C. by gentle stirring. Pentaerythritol tetranitrate (PETN) (1200 grams), wet with 63 grams of water at 23° C., was incorporated in the same manner, stirring having been accomplished with a wooden spatula. The PETN was a crude grade obtained by nitrating pentaerythritol, washing to neutralize the surface, and drying. The temperature of the emulsion then was 30° C.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04343663uspto-grants-1982_08