Reaktion #94458

ord-40b8cd088f1640418279c0a064ef507d

Reaktionsgleichung

c1ccc(OCCCCOc2ccccc2)cc1
1,4-Diphenoxy-n-butane
O=C(Cl)c1ccccc1
benzoyl chloride
[Al+3].[Cl-].[Cl-].[Cl-]
aluminum chloride
→
O=C(c1ccccc1)c1ccc(OCCCCOc2ccc(C(=O)c3ccccc3)cc2)cc1
crystals
O=C(c1ccccc1)c1ccc(OCCCCOc2ccc(C(=O)c3ccccc3)cc2)cc1
1,4-Bis(4-benzoylphenoxy)butane

Edukte

c1ccc(OCCCCOc2ccccc2)cc1
1,4-Diphenoxy-n-butane
O=C(Cl)c1ccccc1
benzoyl chloride
[Al+3].[Cl-].[Cl-].[Cl-]
aluminum chloride

Reagenzien

Keine

Lösungsmittel

ClCCCl
1,2-dichloroethane

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

1,4-Diphenoxy-n-butane (24.2 g) and benzoyl chloride (29 g) are reacted in 250 ml of 1,2-dichloroethane in the presence of aluminum chloride (28 g) for 4 hours at 60° to yield 18.3 g (41% of theory) of colorless crystals mp 163°-4°. Calculated for C30H26O4 : C, 79.98% H, 5.82%. Found: C, 80.16%; H, 5.98%.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04130664uspto-grants-1978_12