Reaktion #944049

ord-01e8315078304df19cb80ab97cdd960f

Reaktionsgleichung

O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Sr+2]
strontium nitrate
CCc1c(CP(=O)([O-])[O-])cc(C(C)(C)C)c(O)c1C(C)(C)C.[Na+].[Na+]
sodium (o-ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate)
→
CCc1c(CP(=O)([O-])[O-])cc(C(C)(C)C)c(O)c1C(C)(C)C.CCc1c(CP(=O)([O-])[O-])cc(C(C)(C)C)c(O)c1C(C)(C)C.[Sr+2].[Sr+2]
strontium bis(o-ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate)

Edukte

O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Sr+2]
strontium nitrate
CCc1c(CP(=O)([O-])[O-])cc(C(C)(C)C)c(O)c1C(C)(C)C.[Na+].[Na+]
sodium (o-ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate)
—
aqueous solution

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    workup.STIRRINGAfter the mixture was stirred for 1 hour
  2. 2
    Sonstigethe precipitates were separated by filtration
  3. 3
    Waschenwashed with water
  4. 4
    Sonstigedried

Vorschrift

ml aqueous solution of 317 mg (1.5 mmol) strontium nitrate was added dropwise to 7.5 ml aqueous solution of 1 g (2.85 mmol) sodium (o-ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate) (phosphorus compound C described above) at room temperature under stirring. After the mixture was stirred for 1 hour, the precipitates were separated by filtration, washed with water and dried to give strontium bis(o-ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate), 513 mg (48 %).

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07144614B2uspto-grants-2006_12