Reaktion #944048

ord-35468e7a7df84ebd9632a64bdaf79801

Reaktionsgleichung

O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Mg+2]
magnesium nitrate
CCc1c(CP(=O)([O-])[O-])cc(C(C)(C)C)c(O)c1C(C)(C)C.[Na+].[Na+]
sodium (o-ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate)
→
CCc1c(CP(=O)([O-])[O-])cc(C(C)(C)C)c(O)c1C(C)(C)C.CCc1c(CP(=O)([O-])[O-])cc(C(C)(C)C)c(O)c1C(C)(C)C.[Mg+2].[Mg+2]
magnesium bis(o-ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate)

Edukte

O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Mg+2]
magnesium nitrate
CCc1c(CP(=O)([O-])[O-])cc(C(C)(C)C)c(O)c1C(C)(C)C.[Na+].[Na+]
sodium (o-ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate)
—
aqueous solution

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    workup.STIRRINGAfter the mixture was stirred for 1 hour
  2. 2
    Filtrationthe precipitates were collected by filtration
  3. 3
    Waschenwashed with water
  4. 4
    Sonstigedried

Vorschrift

ml aqueous solution of 192 mg (0.75 mmol) magnesium nitrate.6H2O was added dropwise to 4 ml aqueous solution of 500 mg (1.4 mmol) sodium (o-ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate) (phosphorus compound C described above) at room temperature under stirring. After the mixture was stirred for 1 hour, the precipitates were collected by filtration, washed with water and dried to give magnesium bis(o-ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate), 359 mg (74%).

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07144614B2uspto-grants-2006_12