Reaktion #93595

ord-86d99ad2c96d423794886a4f3cc76510

Reaktionsgleichung

C/C=C(/C)C(=O)OC
methyl angelate
CC/C=C\CCO
(Z)-3-hexenyl alcohol
CCCCCCCCCCCC(=O)[O-].CCCCCCCCCCCC(=O)[O-].CCCCCCC[CH2][Sn+2][CH2]CCCCCCC
dioctyltin laurate
→
C/C=C(/C)C(=O)OCC/C=C\CC
(Z)-3-Hexenyl Angelate

Edukte

—
4A
C/C=C(/C)C(=O)OC
methyl angelate
CC/C=C\CCO
(Z)-3-hexenyl alcohol
CCCCCCCCCCCC(=O)[O-].CCCCCCCCCCCC(=O)[O-].CCCCCCC[CH2][Sn+2][CH2]CCCCCCC
dioctyltin laurate

Reagenzien

Keine

Lösungsmittel

Cc1ccccc1
toluene

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    workup.ADDITIONA mixture of 20.0 g
  2. 2
    Sonstigeglass flask, which was equipped with a Soxhlet extractor

Vorschrift

A mixture of 20.0 g. of methyl angelate, 26.34 g. of (Z)-3-hexenyl alcohol, 100 ml. of toluene and 1.2 g. of dioctyltin laurate was placed in a 300 ml. glass flask, which was equipped with a Soxhlet extractor filled on the top with molecular sieve 4A and a reflux cooler.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04613680uspto-grants-1986_09