Reaktion #93593

Reaktionsgleichung

methyl angelate

3-methyl-2-butenyl alcohol

dioctyltin laurate

→

3-methyl-2-butenyl angelate

Lösungsmittel

toluene

Reaktionsbedingungen

Aufarbeitung

1. 1
   workup.ADDITIONA mixture of 19.6 g
2. 2
   Sonstigewhich was equipped with a Soxhlet extractor
3. 3
   TemperaturThe mixture was heated
4. 4
   Temperaturunder reflux
5. 5
   SonstigeThe mixture obtained from the heating for a total of 26 hours
6. 6
   workup.DISTILLATIONwas subjected to single distillation
7. 7
   Sonstigeto give 24.24 g

Vorschrift

A mixture of 19.6 g. of methyl angelate, 22.2 g. of 3-methyl-2-butenyl alcohol, 100 ml. of toluene and 1.6 g. of dioctyltin laurate was placed in a glass flask which was equipped with a Soxhlet extractor filled with molecular sieve 4A on the top and a reflux cooler. The mixture was heated under reflux while returning the refluxed liquid through the molecular sieve 4A to the flask. The mixture obtained from the heating for a total of 26 hours was subjected to single distillation to give 24.24 g. of a distillate boiling at 102°-105° C. (25 mmHg).

Quelle