Reaktion #82152

Reaktionsgleichung

2-Methyl-homophthalimide

phenylthiomethyl vinyl ketone

3(2H)-Phenanthridinone

homophthalimide

→

2-methyl-4-(3'-oxo-4'-phenylthiobutyl)-homophthalimide

Reaktionsbedingungen

Aufarbeitung

1. 1
   Sonstigeprepared by the method A

Vorschrift

3(2H)-Phenanthridinone derivatives have been prepared from homophthalimide by the method of H. Iida et al., (Heterocycles 1983, 20, 227-30). 2-Methyl-homophthalimide is reacted with phenylthiomethyl vinyl ketone (prepared by the method A. G. Schultz et al.,J. Am. Chem. Soc. 1978, 100, 2140-9) in the presence of Triton B according to the described method to form 2-methyl-4-(3'-oxo-4'-phenylthiobutyl)-homophthalimide 9.

Quelle