Reaktion #806262

ord-fc90dcaa79f548298fe76ba67b91ec5b

Reaktionsgleichung

CC(C)C(O)C(C)(C)CO
2,2,4-trimethylpentan-1,3-diol
CC(C)=CCCl
prenyl chloride
→
CC(C)=CCOCC(C)(C)C(O)C(C)C
1-(3-methyl-2-butenyloxy)-2,2,4-trimethylpentan-3-ol
Ausbeute 92.0%

Edukte

CC(C)C(O)C(C)(C)CO
2,2,4-trimethylpentan-1,3-diol
CC(C)=CCCl
prenyl chloride

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Treatment of 2,2,4-trimethylpentan-1,3-diol with prenyl chloride employing the alkylation reaction conditions described above provided 1-(3-methyl-2-butenyloxy)-2,2,4-trimethylpentan-3-ol in 92.0% yield (393.8 g, b.p.=82–84 C./0.8 mmHg).

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07132391B2uspto-grants-2006_11