Reaktion #797654

ord-2abe0e9771bf47f3b6e4f093ccec56c1

Reaktionsgleichung

O=C(O)c1ccc(I)nc1
6-iodonicotinic acid
CCCc1ccc(C(=O)O)cc1I
3-iodo-4-propylbenzoic acid
CC#Cc1ccc(C(=O)O)cn1
title compound
Ausbeute 45.0%
CC#Cc1ccc(C(=O)O)cn1
6-(Prop-1-ynyl)nicotinic acid
Ausbeute 45.0%

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

When 6-iodonicotinic acid was substituted for the 3-iodo-4-propylbenzoic acid in Example 47, Step B, the similar process afforded the title compound in 45% yield, as yellow solid. 1H-NMR (CDCl3) 2.12 (s, 3H); 7.25 (broad s, 1H+H2O); 7.46 (dd, 1H, J=0.6, 7.6 Hz); 8.2 (dd, 1H, J=2.16, 6 Hz); 9.23 (dd, 1H, J=0.8, 1.4 Hz).

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US09181182B2uspto-grants-2015_11