Reaktion #75672

ord-638a400385b2400ca3182ab90c300c27

Reaktionsgleichung

[Na+].[OH-]
sodium hydroxide
Nc1cc(Cl)cc(Cl)c1
3,5-dichloroaniline
CCC(=O)C(=O)[O-]
ethylglyoxalate
C=Cc1ccc(Br)cc1
4-bromostyrene
O=C(O)C(F)(F)F
trifluoroacetic acid
O=C(O)C1CC(c2ccc(Br)cc2)c2c(Cl)cc(Cl)cc2N1
Compound 40
O=C(O)C1CC(c2ccc(Br)cc2)c2c(Cl)cc(Cl)cc2N1
4-(4-bromophenyl)-5,7-dichloro-1 ,2,3,4-tetrahydroquinoline-2-carboxylic Acid

Lösungsmittel

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Compound 40 was prepared by the basic process from 5.0 mmol 3,5-dichloroaniline, 5.5 mmol ethylglyoxalate solution (50% toluene), 15.0 mmol 4-bromostyrene and 5.0 mmol trifluoroacetic acid in 30.0 ml acetonitrile. Subsequent saponification was carried out using 1.0 ml of sodium hydroxide solution (6N water) in 20.0 ml of ethanol.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06699877B2uspto-grants-2004_03