Reaktion #75648

ord-d3e2222c3045443591698a2b7c600b99

Reaktionsgleichung

[Na+].[OH-]
sodium hydroxide
Nc1cc(Cl)cc(Cl)c1
3,5-dichloroaniline
CCC(=O)C(=O)[O-]
ethylglyoxalate
C=Cc1ccccc1
styrene
O=C(O)C(F)(F)F
trifluoroacetic acid
O=C(O)C1CC(c2ccccc2)c2c(Cl)cc(Cl)cc2N1
Compound 15
O=C(O)C1CC(c2ccccc2)c2c(Cl)cc(Cl)cc2N1
5,7-dichloro-4-phenyl-1,2,3,4-tetrahydroquinoline-2-carboxylic Acid

Lösungsmittel

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Compound 15 was prepared by the basic process from 5.0 mmol 3,5-dichloroaniline, 5.5 mmol ethylglyoxalate solution (50% toluene), 15.0 mmol styrene and 5.0 mmol trifluoroacetic acid in 30.0 ml acetonitrile. Subsequent saponification was carried out using 1.0 ml of sodium hydroxide solution (6N water) in 20.0 ml of ethanol.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06699877B2uspto-grants-2004_03