Reaktion #75025

ord-e6f33265221e4ce2b908362c62e1a51c

Reaktionsgleichung

CCC(=O)O
propionic acid
C=CCCCCCC
Octene-1
CCC(=O)[O-].[K+]
potassium propionate
CCCCCCC1CC(C)C(=O)O1
alphamethyl-gamma-n-hexyl-butyrolactone

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Octene-1 in an amount of 2.24 g. and 11.65 g. of manganic acetate, Mn(C2H3O2)3.2H2O, (comprising two equivalents of Mn+3 based on titration value), were refluxed under nitrogen in 200 ml. propionic acid containing 20 g. potassium propionate. In less than an hour a good yield of alphamethyl-gamma-n-hexyl-butyrolactone was obtained.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04175089uspto-grants-1979_11